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4.1 Therapeutic potential of classical antioxidants Antioxidants play a central role in cellular defense against OS by scavenging ROS and their precursors, suppressing ROS generation, and chelating metal ions that catalyze ROS-forming reactions ( 2 O 2 derived from both exogenous and endogenous sources ( 2 O 2 and effectively inhibits lipid peroxidation ( Although individual antioxidant enzymes are often associated with distinct catalytic functions, they typically operate in a coordinated manner within biological systems to form functional redox cascades ( Despite decades of intensive research aimed at the pharmaceutical development of antioxidant enzymes, particularly SOD-based therapeutics, clinical translation has remained largely unsuccessful