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Expired glutathione is unlikely to cause new side effects, but if the ingredients have significantly degraded or the fats in a liposomal formula have turned rancid, it could lead to digestive upset or nausea

By removing hydroperoxides (LOOH), which occur during the first phase of lipid peroxidation, by activity of glutathione-dependent peroxidase which catalyzes reduction of hydroperoxide into the corresponding alcohol, the reactions of lipid peroxidation propagation can be prevented

Bioorg Med Chem Lett 14(13):34513455 Keillor JW, Menard A, Castonguay R et al (2004) Pre-steady-state kinetic studies of rat kidney gamma-glutamyl transpeptidase confirm its ping-pong mechanism

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